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Why Does Dry-Erase Marker Wipe Off a Whiteboard When Permanent Marker Won't?

Category: Technology

Write on a whiteboard, rub it with a cloth, and the line is gone. Write on the same board with a permanent marker and it stays put. What makes dry-erase ink different?

The short answer, from patents: dry-erase writing is not destroyed when you wipe it. In the patents described here, the ink dries on top of a slippery layer, so wiping lifts it from the board. The rest of the article looks at what that layer is, and why writing left for a long time can become hard to remove. [1] [2]

1. Where Does Dry-Erase Writing Go When You Wipe It?

On paper, ink soaks into the tiny gaps between fibers, so rubbing the surface cannot pull it back out. A whiteboard is different. Its surface is smooth and does not absorb liquids, so the ink has nowhere to go but to stay on top.

A BIC patent defines a dry-erasable ink as one that "can be dry-erased on the support, even after drying, simply by rubbing." [2] In other words, no water or cleaning spray is needed. Rubbing is enough.

So the writing can be removed by rubbing after it has dried. The patent does not say exactly how the ink moves to the cloth, so that part is left open. The next question is what lets the ink come off the board this way.

2. How Does a Slippery Layer in the Ink Keep It from Gripping the Board?

An early patent from the Gillette company, granted in 1976, describes the idea clearly. The ink contains a "release agent" dissolved in its liquid. As the liquid evaporates, the release agent separates from it and "forms a film on the marking surface." The coloring material is chosen so that it does not dissolve in the release agent, so it "lie[s] on top of the thin film." Because of this, the patent explains, the color is not in contact with the surface of the board, and it can be erased. [1]

A simple way to picture it is a layer of cooking oil between a sticker and a table: the sticker sits there, but it does not really grip. This is only an analogy, not something the patents say.

The same patent lists what a good release agent needs, including that it evaporates very little at room temperature, mixes fully into the ink, does not dissolve the colorants, and is nearly colorless so it does not hide the color. [1] These patents do not discuss permanent markers, so they cannot tell us how a permanent marker differs.

3. What Else Is in Dry-Erase Ink Besides the Release Agent?

The release agent is only one part. The BIC patent (published in 2022) describes an alcohol-based ink. The liquid part is mostly alcohol, between 40% and 90% of the ink by weight, with ethanol and propanol given as the choices. Pigment makes up 0.1% to 10%, and a resin, polyvinyl butyral in its examples, makes up 0.1% to 10% as well. [2]

After the alcohol evaporates, the resin forms a film together with the pigment. [2] A Japanese patent claim for a wipe-off writing-board ink lists the same kinds of parts: an alcohol and/or glycol solvent, a colorant, a resin, and special additives. [4]

Putting it together, a line of dry-erase writing seems to be a thin film of pigment and resin sitting on a slippery layer. These are examples from particular patents, not recipes for every pen on the market.

4. Why Do Some Inks Use Several Release Agents Together?

The BIC patent uses three: glycerol, a glycol (triethylene glycol in its example), and a pentaerythritol ester. It says that these three "present a synergy if used together," meaning they work better as a team than the effects of each alone would suggest. [2]

The patent explains why it bothered. Earlier inks that used the ester alone erased well over time only on certain surfaces: polypropylene, PVC, and enamel. [2] The patent describes the combined recipe as an improvement, but it states the effect rather than explaining the mechanism, so how the three work together is not something we can say. It is also one company's patent, and other makers may use different ingredients.

This suggests that ink makers must choose ingredients carefully, and that different boards may need different answers.

5. Why Does Old Writing Become Harder to Wipe Off?

Anyone who has left a board unused for a while may have seen writing that smears or leaves a faint shadow. A 1990 US patent from Sakura Color Products says earlier erasable inks formed writing "not readily erased when the writings are left standing for a long period." It adds that such writing was scarcely erasable on impervious surfaces, especially on a fluorocarbon resin surface. [3]

Its own idea was to add oily liquids so that a liquid layer forms where the writing touches the board, with the pigment-containing resin film on top. The patent says this makes the ink much easier to erase after long standing, though it adds that the inventors do not claim this explanation is proven. [3] The BIC patent also notes that users may want to erase boards "even after several days, weeks or even months." [2]

None of these sources gives a number of days after which writing becomes stuck, so none is given here. What the patents do support is simple: the slippery layer works best under certain conditions, and the board material and the length of time both matter.

6. How Can You Compare Fresh and Older Writing Yourself?

If you have a whiteboard at home or school, ask an adult first and open a window if the pen smells strong. Use only pens made for whiteboards.

In a corner, draw two lines. Wipe the first one right away with a dry tissue. Wipe the second one after a day, using about the same pressure. Then look at two things: how easily each line came off, and whether the tissue picked up any color.

You may see no difference, because pens and boards vary a lot. Even so, you will have tested the same question the patents were trying to solve. To go deeper, read the Gillette patent for the basic idea and the Sakura patent for the problem of long-standing writing.

Sources

Sources: patent documents. Where a patent explains a mechanism, it is one company's explanation and not a guarantee about every pen.

  1. US Patent 3,949,132, "Marking boards and erasable ink compositions therefor," Gillette Co. (granted April 6, 1976) https://patents.google.com/patent/US3949132A/en (Release agent forms a film; dyes lie on top; requirements for a release agent. The first 100,000 of about 128,000 characters were read through an extraction tool; the rest was not.)
  2. US Patent 11,286,397 B2, "Alcohol-based dry-erasable ink," Société BIC (granted March 29, 2022) https://patents.google.com/patent/US11286397B2/en (Definition of dry-erasable, composition ranges, film formation, three-agent combination. Read through an extraction tool that returned quotations from the description, not the whole text by eye. The patent states effects, not the mechanism of the combination.)
  3. US Patent 4,954,174, "Erasable ink compositions," Sakura Color Products Corp. (published September 4, 1990) https://patents.google.com/patent/US4954174A/en (Problem of writing left standing; liquid layer under the resin film. Read through an extraction tool. Its Japanese counterpart, JPH086062B2, was checked only for its claim.)
  4. Japanese patent JPH0569869B2, "筆記板用マーキングインキ" (published October 1, 1993) https://patents.google.com/patent/JPH0569869B2/ja (Only the claims were read: solvent, colorant, resin, additives. The patent is in Japanese.)

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